Through multiscale analyses we introduce harvesting of resonant optical phonons in semiconductors, with three new concepts:
• phonon recycling (absorption) in in graded heterojuction for partial reversal of the joule heating,
• phonovoltaic for direct hot-phonon-energy conversion, and
• phonocatalysis with phonon-controlled chemisorbed dissociation.
In reversing the joule heating through in-situ phonon recycling (pR), we tune a heterojunction barrier height to optical phonons and optimize it for GaAs:Al electron channel for maximum phonon absorption. We calculate the pR efficiency of this partial reversal of phonon emission.
In phonovoltaic (pV) with nonequilibrium optical phonon source and phonon generation of charge pairs in p-n junction to generate power, we define the pV figure of merit and explore the optimal material for efficient room-temperature pV. We search for pV materials and tune the partially-hydrogenated graphite (Hx-hC1-x) bandgap to its C=C bond optical phonons and evaluate the efficiency.
In phonocatalysics (pC) with ab initio molecular dynamics we show the chemisorbed dissociation of XeF6 on h-BN surface leads to formation of XeF4 and two surface F/h-BN bonds. We show that the chemisorbed dissociation (the pathway activation ascent) requires absorption of large-energy optical phonons. Then using progressively heavier isotopes of B and N atoms, we show that limiting these high-energy optical phonons inhibits the chemisorbed dissociation, i.e., controllable pC.
More about the Speaker: Massoud Kaviany (Ph.D. UC-Berkeley 1979) is a Professor in the Department of Mechanical Engineering and in the Applied Physics Program at the University of Michigan since 1986. His interest is in heat transfer physics. He has authored Heat Transfer Physics, 2nd Edition 2014 and Essentials of Heat Transfer 2011, by Cambridge University Press. He was Chair of ASME Committee on Theory and Fundamental Research in Heat Transfer, is Associate Editor of Nanoscale and Microscale Thermophysical Engineering, ASME Life Fellow and APS Fellow, and recipient of University of Michigan Engineering 2003 Education Excellence Award, ASME 2002 Heat Transfer Memorial Award (Science), 2010 Harry Potter Gold Medal (Thermodynamics Science), and 2013 HTD 75th Anniversary Medal.